Flow analysis of hydrogen peroxide with a dye-formation reaction catalyzed by an ion-exchange resin modified with Mn3+-tetrakis(sulfophenyl)porphine

被引：10

作者：

Mifune, M

Mukuno, T

Tani, M

Iwado, A

Odo, J

Motohashi, N

Saito, Y ^{[1
]}

机构：

[1] Okayama Univ, Fac Pharmaceut Sci, Okayama 700, Japan

[2] Okayama Univ, Grad Sch Nat Sci & Technol, Okayama 700, Japan

[3] Kobe Pharmaceut Univ, Kobe, Hyogo 658, Japan

来源：

ANALYTICAL SCIENCES | 1998年 / 14卷 / 03期

关键词：

flow injection analysis; hydrogen peroxide; anion-exchange resin modified with manganese(III)-tetrakis(sulfophenyl)porphine; 4-aminoantipyrine; 4-chlorophenol;

D O I：

10.2116/analsci.14.519

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The present flow analysis of hydrogen peroxide is based on a measurement of the absorbance of quinoid-dye formed by a following reaction (1) using an anion-exchange resin modified with manganese(III)-tetrakis(sulfophenyl)porphine (Mn-TSPPr), which catalyzes the reaction (1), just like an immobilized peroxidase: 4-aminoantipyrine+4-chlorophenol+2H(2)O(2) (Ma-TSPPr) under right arrow quinoid dye+4H(2)O [reaction (1)]. Mn-TSPPr is more advantageous than immobilized peroxidase in terms of storage and stability for both temperature and moisture. The present facilitated method is satisfactory in reproducibility and sensitivity.

引用

页码：519 / 522

页数：4

共 12 条

[1]

DAMAGK GF, 1968, ANAL BIOCHEM, V22, P219

[2] PHOTOCHEMISTRY OF MANGANESE PORPHYRINS .1. CHARACTERIZATION OF SOME WATER-SOLUBLE COMPLEXES [J].

HARRIMAN, A ;

PORTER, G .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS II, 1979, 75 :1532-1542

[3]

KAMOUN P, 1976, CLIN CHEM, V22, P964

[4]

MORIN LG, 1973, CLIN CHEM, V19, P959

[5]

PASTERNACK RF, 1984, INORG CHEM, V19, P345

[6]

SAITO Y, 1986, CHEM PHARM BULL, V34, P2885

[7]

SAITO Y, 1986, CHEM PHARM BULL, V34, P5016

[8] DETERMINATION OF HYDROGEN-PEROXIDE WITH N,N-DIETHYLANILINE AND 4-AMINOANTIPYRINE BY USE OF AN ANION-EXCHANGE RESIN MODIFIED WITH MANGANESE TETRAKIS(SULFOPHENYL)PORPHINE, AS A SUBSTITUTE FOR PEROXIDASE [J].

SAITO, Y ;

MIFUNE, M ;

NAKASHIMA, S ;

ODO, J ;

TANAKA, Y ;

CHIKUMA, M ;

TANAKA, H .

TALANTA, 1987, 34 (07) :667-669

[9] DETERMINATION OF HYDROGEN-PEROXIDE BY USE OF AN ANION-EXCHANGE RESIN MODIFIED WITH MANGANESE TETRAKIS (SULFOPHENYL) PORPHINE AS A MIMESIS OF PEROXIDASE [J].

SAITO, Y ;

NAKASHIMA, S ;

MIFUNE, M ;

ODO, J ;

TANAKA, Y ;

CHIKUMA, M ;

TANAKA, H .

ANALYTICA CHIMICA ACTA, 1985, 172 (JUN) :285-287

[10]

SAITO Y, 1987, CHEM PHARM BULL, V35, P862

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