Very large neutral and polyanionic Fe/Au cluster-containing dendrimers

被引:17
作者
Benito, M
Rossell, O
Seco, M
Segalés, G
Maraval, V
Laurent, R
Caminade, AM
Majoral, JP
机构
[1] Univ Barcelona, Dept Quim Inorgan, E-08028 Barcelona, Spain
[2] CNRS, Chim Coordinat Lab, F-31077 Toulouse 4, France
关键词
iron; gold; phosphorus; dendrimer; cluster;
D O I
10.1016/S0022-328X(00)00698-7
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Treatment of tetrahydrofuran solutions of a series of ClAu-terminated dendrimers with the iron anions [Fe-2(CO)(7)(PPh2)](-) and Fe-3(CO)(11)](2-) has allowed the new dendrimer species decorated on the surface by Fe2Au or Fe2Au units to be isolated, including one having up to 192 Fe2Au clusters. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:33 / 37
页数:5
相关论文
共 25 条
[1]   Introduction of the cluster fragment Ru3(CO)11 at the periphery of phosphine dendrimers catalyzed by the electron-reservoir complex [FeICp(C6Me6)] [J].
Alonso, E ;
Astruc, D .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (13) :3222-3223
[2]   Carbosilane dendrimers functionalized with AuFe3 clusters [J].
Benito, M ;
Rossell, O ;
Seco, M ;
Segalés, G .
INORGANICA CHIMICA ACTA, 1999, 291 (1-2) :247-251
[3]   MALDI TOF mass spectrometry for the characterization of phosphorus-containing dendrimers. Scope and limitations [J].
Blais, JC ;
Turrin, CO ;
Caminade, AM ;
Majoral, JP .
ANALYTICAL CHEMISTRY, 2000, 72 (20) :5097-5105
[4]   About dendrimers: Structure, physical properties, and applications [J].
Bosman, AW ;
Janssen, HM ;
Meijer, EW .
CHEMICAL REVIEWS, 1999, 99 (07) :1665-1688
[5]   The synthesis and properties of novel functional dendritic molecules [J].
Chow, HF ;
Mong, TKK ;
Nongrum, MF ;
Wan, CW .
TETRAHEDRON, 1998, 54 (30) :8543-8660
[6]   Divergent assembly of a starburst tetracosacobalt compound [J].
Constable, EC ;
Eich, O ;
Housecroft, CE ;
Johnston, LA .
CHEMICAL COMMUNICATIONS, 1998, (23) :2661-2662
[7]  
CONSTABLE EC, 1999, CHEM COMMUN, P1363
[8]  
FEEDER N, ANGEW CHEM INT ED, V39, P1661
[9]   ANIONS [FE2(CO)8]2- AND [FE2(CO)6(MU-CO) (MU-PPH2)]- AS BUILDING-BLOCKS FOR THE SYNTHESIS OF MIXED-METAL CLUSTERS - CRYSTAL-STRUCTURE OF [FE2(CO)6(MU-CO)(MU-PPH2)(MU-CU(PPH3))] [J].
FERRER, M ;
REINA, R ;
ROSSELL, O ;
SECO, M ;
SOLANS, X .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, (02) :347-349
[10]  
Fischer M, 1999, ANGEW CHEM INT EDIT, V38, P885, DOI 10.1002/(SICI)1521-3773(19990401)38:7<884::AID-ANIE884>3.0.CO