Ordered porous polymer films via phase separation in humidity environment

被引：73

作者：

Cui, L ^{[1
]}

Peng, J ^{[1
]}

Ding, Y ^{[1
]}

Li, X ^{[1
]}

Han, YC ^{[1
]}

机构：

[1] Chinese Acad Sci, Changchun Inst Appl Chem, Grad Sch, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China

来源：

POLYMER | 2005年 / 46卷 / 14期

基金：

中国国家自然科学基金;

关键词：

ordered porous films; phase separation; breath figures;

D O I：

10.1016/j.polymer.2005.04.018

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A transition of morphology from island-like structure to disordered and ordered holes on the surface of polystyrene (PS) and poly(2-vinylpyridine) (PVP) blend films were observed with the increase of humidity. At appropriate weight ratio of PS/PVP and PS molecular weight, when humidity reached to a critical value, the hexagonal arrays of holes formed for PS/PVP blend films due to 'breath figures' stabilized by PVP with its strong hygroscopic characteristics during phase separation. (c) 2005 Elsevier Ltd. All rights reserved.

引用

页码：5334 / 5340

页数：7

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