A wetting layer breaks the ice rules

被引：19

作者：

Feibelman, PJ ^{[1
]}

机构：

[1] Sandia Natl Labs, Surface & Interface Sci, Albuquerque, NM 87185 USA

来源：

CHEMICAL PHYSICS LETTERS | 2005年 / 410卷 / 1-3期

关键词：

D O I：

10.1016/j.cplett.2005.05.026

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Ab initio, calculations for a water layer on Ru(0 0 0 1) predict that to preserve O-Ru bonds, a substantial percentage of weaker, O-(HO)-O-... bonds will optimally be broken, even in its ground state. Thus, the axiom that wetting only occurs if water molecules bind more strongly to a surface than to each other is fundamental to understanding this wetting layer's structure. X-ray photoelectron spectra confirm the present prediction of similar to 6.7% broken H-bonds in the wetting layer at 150 K. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：120 / 124

页数：5

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