A versatile route to [Ru-3(CO)(11)(alkyne)] complexes

被引：8

作者：

Aime, S

Dastru, W

Gobetto, R

Milone, L

Viale, A

机构：

[1] Dipartimento di Chimica Inorganica, Chim. Fisica e Chimica dei Materiali, 10125 Torino

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 03期

关键词：

D O I：

10.1039/a606984c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Alkynes react at low temperature with [RU(3)H(mu-H)(CO)(11)] to afford the novel [Ru-3(CO)(11)(alkyne)] complexes, which correspond to the first stage of the coordination of alkynes to metal-clusters and are the precursors of the previously reported [Ru-3(CO)(9)(mu-CO)(mu(3)-eta(2)-alkyne)] derivatives.

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收藏

页码：267 / 268

页数：2

相关论文

共 19 条

[1]

ADAMS AD, 1982, COMPREHENSIVE ORGANO, P1025

[2] EVALUATION OF THE ENERGY BARRIER FOR CARBONYL EXCHANGE IN THE HIGHLY FLUXIONAL RU-3(CO)(12) SYSTEM [J].

AIME, S ;

DASTRU, W ;

GOBETTO, R ;

KRAUSE, J ;

MILONE, L .

ORGANOMETALLICS, 1995, 14 (09) :4435-4438

[3] SYNTHESIS, REACTIVITY, AND LIGAND DYNAMICS OF RU3(CO)9(MU-CO)(MU-3-ETA-2-ALKYNE) COMPOUNDS [J].

AIME, S ;

GOBETTO, R ;

MILONE, L ;

OSELLA, D ;

VIOLANO, L ;

ARCE, AJ ;

DESANCTIS, Y .

ORGANOMETALLICS, 1991, 10 (08) :2854-2856

[4]

AIME S, IN PRESS

[5] STRUCTURE OF AND BONDING IN AN ALKYNE-NONACARBONYLTRIIRON COMPLEX . A NEW TYPE OF IRON-ACETYLENE INTERACTION [J].

BLOUNT, JF ;

DAHL, LF ;

HOOGZAND, C ;

HUBEL, W .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1966, 88 (02) :292-&

[6] PI-COMPLEXES OF PLATINUM(II) WITH UNSATURATED HYDROCARBONS .2. CRYSTAL AND MOLECULAR STRUCTURE OF TRANS-DICHLORO-(PI-DI-TERT-BUTYLACETYLENE)-PARA-TOLUIDINEPLATINUM(II) [J].

DAVIES, GR ;

OWSTON, PG ;

HEWERTSON, W ;

MAIS, RHB ;

PATEL, CG .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1970, (11) :1873-+

[7]

DEEMING AJ, 1986, ADV ORGANOMET CHEM, V26, P1

[8] REACTIONS OF ACETYLENE, METHYL-SUBSTITUTED AND PHENYL-SUBSTITUTED ACETYLENES, AND ETHYLENE WITH 1,1,1,1,2,2,2,3,3,3-DECACARBONYL-2,3-DI-MU-HYDRIDO-TRI-ANGULO-TRIOSMIUM [J].

DEEMING, AJ ;

HASSO, S ;

UNDERHILL, M .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1975, (15) :1614-1620

[9] METAL CLUSTER-INDUCED ELECTROPHILICITY OF ARENES [J].

GALLOP, MA ;

JOHNSON, BFG ;

LEWIS, J ;

WRIGHT, AH .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1989, (03) :481-487

[10]

HARRIS RK, 1983, NUCLEAR MAGNETIC RES