A 3-D noninterpenetrating diamondoid network of a decanuclear copper(I) complex

被引：84

作者：

Cheng, JK

Chen, YB

Wu, L

Zhang, J

Wen, YH

Li, ZJ

Yao, YG ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China

[2] Fuzhou Univ, Dept Chem, Fujian 350002, Peoples R China

来源：

INORGANIC CHEMISTRY | 2005年 / 44卷 / 10期

关键词：

D O I：

10.1021/ic050301f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The solvothermal reaction of CuCl2 center dot 2H(2)O with pyridine-4-thiol and ethanol yielded a novel photoluminescent 3-D polymeric complex with an interesting decorated diamondoid network that is constructed of decanuclear copper(I) cluster units and mu(4)-Cl ligands. The in situ generation of CuSO4 center dot 5H(2)O implies the spontaneous occurrence of desulfurization and redox reactions in the present system.

引用

页码：3386 / 3388

页数：3

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