Self-assembly of bidentate ligands for combinatorial homogeneous catalysis based on an A-T base-pair model

被引：127

作者：

Breit, B ^{[1
]}

Seiche, W ^{[1
]}

机构：

[1] Univ Freiburg, Inst Organ Chem & Biochem, D-79104 Freiburg, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 11期

关键词：

combinatorial chemistry; homogeneous catalysis; hydroformylation; rhodium; self-assembly;

D O I：

10.1002/anie.200462499

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The odd couple: Inspired by the principle of DNA base pairing a conceptually new approach for the generation of a heterobidentate-ligand library based on self-assembly through hydrogen-bonding is realized. From a 4 x 4 library a catalyst that shows outstanding activity and excellent regioselectivity could be identified (see scheme; FGR = functional group, Do = donor group). (Chemical Equation Presented) © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：1640 / 1643

页数：4

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