Static energy calculations of stress-strain behavior of self-assembled monolayers

被引：22

作者：

Henda, R ^{[1
]}

Grunze, M ^{[1
]}

Pertsin, AJ ^{[1
]}

机构：

[1] Univ Heidelberg, D-69120 Heidelberg, Germany

来源：

TRIBOLOGY LETTERS | 1998年 / 5卷 / 2-3期

关键词：

static energy calculations; self-assembled monolayers; stress-strain behavior;

D O I：

10.1023/A:1019141708230

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

The mechanical response of alkanethiol/Au(111) self-assembled monolayers to normal stress is simulated using the static energy minimization technique. The calculation results are discussed in terms of stress-induced structural changes, stress-strain relationships and Young's moduli. The dependence of the calculated elastic properties on the monolayer configuration, force field, and chain length is examined.

引用

收藏

页码：191 / 195

页数：5

相关论文

共 25 条

[1] DOMAIN AND MOLECULAR SUPERLATTICE STRUCTURE OF DODECANETHIOL SELF-ASSEMBLED ON AU(111) [J].

ANSELMETTI, D ;

BARATOFF, A ;

GUNTHERODT, HJ ;

DELAMARCHE, E ;

MICHEL, B ;

GERBER, C ;

KANG, H ;

WOLF, H ;

RINGSDORF, H .

EUROPHYSICS LETTERS, 1994, 27 (05) :365-370

[2] SUPERLATTICE STRUCTURE AT THE SURFACE OF A MONOLAYER OF OCTADECANETHIOL SELF-ASSEMBLED ON AU(111) [J].

CAMILLONE, N ;

CHIDSEY, CED ;

LIU, GY ;

SCOLES, G .

JOURNAL OF CHEMICAL PHYSICS, 1993, 98 (04) :3503-3511

[3] Golden interfaces: The surface of self-assembled monolayers [J].

Delamarche, E ;

Michel, B ;

Biebuyck, HA ;

Gerber, C .

ADVANCED MATERIALS, 1996, 8 (09) :719-&

[4] REAL-SPACE OBSERVATION OF NANOSCALE MOLECULAR DOMAINS IN SELF-ASSEMBLED MONOLAYERS [J].

DELAMARCHE, E ;

MICHEL, B ;

GERBER, C ;

ANSELMETTI, D ;

GUNTHERODT, HJ ;

WOLF, H ;

RINGSDORF, H .

LANGMUIR, 1994, 10 (09) :2869-2871

[5] CHAIN-LENGTH DEPENDENCE OF THE STRUCTURES AND PHASES OF CH3(CH2)N-1SH SELF-ASSEMBLED ON AU(111) [J].

FENTER, P ;

EISENBERGER, P ;

LIANG, KS .

PHYSICAL REVIEW LETTERS, 1993, 70 (16) :2447-2450

[6] SELF-ASSEMBLY OF N-ALKYL THIOLS AS DISULFIDES ON AU(111) [J].

FENTER, P ;

EBERHARDT, A ;

EISENBERGER, P .

SCIENCE, 1994, 266 (5188) :1216-1218

[7] PREPARATION AND CHARACTERIZATION OF SELF-ASSEMBLED ORGANIC FILMS ON SOLID SUBSTRATES [J].

GRUNZE, M .

PHYSICA SCRIPTA, 1993, T49B :711-717

[8] MOLECULAR-DYNAMICS INVESTIGATIONS OF SELF-ASSEMBLED MONOLAYERS [J].

HAUTMAN, J ;

BAREMAN, JP ;

MAR, W ;

KLEIN, ML .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1991, 87 (13) :2031-&

[9] SIMULATION OF A MONOLAYER OF ALKYL THIOL CHAINS [J].

HAUTMAN, J ;

KLEIN, ML .

JOURNAL OF CHEMICAL PHYSICS, 1989, 91 (08) :4994-5001

[10] MECHANICAL RELAXATION OF ORGANIC MONOLAYER FILMS MEASURED BY FORCE MICROSCOPY [J].

JOYCE, SA ;

THOMAS, RC ;

HOUSTON, JE ;

MICHALSKE, TA ;

CROOKS, RM .

PHYSICAL REVIEW LETTERS, 1992, 68 (18) :2790-2793