Palladium-catalyzed phosphorus-carbon bond formation: cross-coupling reactions of alkyl phosphinates with aryl, heteroaryl, alkenyl, benzylic, and allylic halides and triflates

被引：73

作者：

Bravo-Altamirano, K ^{[1
]}

Huang, ZH ^{[1
]}

Montchamp, JL ^{[1
]}

机构：

[1] Texas Christian Univ, Dept Chem, Ft Worth, TX 76129 USA

来源：

TETRAHEDRON | 2005年 / 61卷 / 26期

基金：

美国国家科学基金会;

关键词：

cross-coupling; hypophosphorous; alkoxysilane; palladium;

D O I：

10.1016/j.tet.2005.03.107

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The direct formation of H-arylphosphinates and related compounds can be accomplished using palladium catalysis. This full paper examines the scope and sonic mechanistic aspects of this phosphorus-carbon bond forming reaction. The reactions of alkenyl and allylic halides are also described for the first time. This novel cross-coupling provides a convenient access to a variety of substituted H-phosphinates. (c) 2005 Elsevier Ltd. All rights reserved.

引用

页码：6315 / 6329

页数：15

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