A new model for the inference of population characteristics from experimental data using uncertainties - Part II. Application to censored datasets

被引:13
作者
Cofino, WP
van Stokkum, IHM
van Steenwijke, J
Wells, DE
机构
[1] Wageningen Univ, Environm Sci Grp, Subdept Water Resources, Hydrol & Quantitat Water Management Grp, NL-6709 PA Wageningen, Netherlands
[2] Vrije Univ Amsterdam, Fac Sci, Div Phys & Astron, Dept Phys Appl Comp Sci, NL-1081 HV Amsterdam, Netherlands
[3] Inst Integrated Inland Water Management & Waste W, RIZA, Minist Transport Publ Works & Water Management, Directorate Gen Publ Works & Water Management, NL-8200 AA Lelystad, Netherlands
[4] Fisheries Res Serv, Aberdeen, Scotland
关键词
censored data; censored samples; left-censored data; maximum likelihood estimation (MLE); detection limit; robust statistics; LOD; LOQ; less than values; mean; standard deviation; interlaboratory studies; proficiency testing;
D O I
10.1016/j.aca.2004.11.008
中图分类号
O65 [分析化学];
学科分类号
070302 [分析化学]; 081704 [应用化学];
摘要
This paper extends a recent report on a model to establish population characteristics to include censored data. The theoretical background is given. The application given in this paper is limited to left-censored data, i.e. less than values, but the principles can also be adopted for other types of censored data. The model gives robust estimates of population characteristics for datasets with complicated underlying distributions including less than values of different magnitude and less than values exceeding the values of numerical data. The extended model is illustrated with simulated datasets, data from interlaboratory studies and temporal trend data on dissolved cadmium in the Rhine river. The calculations confirm that inclusion of left-censored values in the computation of population characteristics improves assessment procedures. (c) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:31 / 39
页数:9
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