Enzymatic synthesis of hydrophilic and hydrophobic derivatives of natural phenolic acids in organic media

被引:123
作者
Stamatis, H [1 ]
Sereti, V [1 ]
Kolisis, FN [1 ]
机构
[1] Natl Tech Univ Athens, Dept Chem Engn, Biosyst Technol Lab, Div 4, Athens 15700, Greece
关键词
cinnamic acids; esterification; lipase; phenolic antioxidants; organic media;
D O I
10.1016/S1381-1177(00)00016-3
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
The enzymatic esterification of natural phenolic antioxidants such as cinnamic acid and benzoic acid derivatives, with aliphatic alcohols, monosaccharides as well as alkylglucosides, using various lipases and esterases in non-aqueous media, was investigated. Reaction rate and esterification yield seems to be Linked to the structural characteristics of the substrates (aromatic acids and alcohols or sugars) used. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:323 / 328
页数:6
相关论文
共 19 条
  • [1] Transglycosylation catalyzed by almond β-glucosidase and cloned Pichia etchellsii β-glucosidase II using glycosylasparagine mimetics as novel acceptors
    Kannan, T
    Loganathan, D
    Bhatia, Y
    Mishra, S
    Bisaria, VS
    [J]. BIOCATALYSIS AND BIOTRANSFORMATION, 2004, 22 (01) : 1 - 7
  • [2] FERULOYL AND PARA-COUMAROYL ESTERASE FROM ANAEROBIC FUNGI IN RELATION TO PLANT-CELL WALL DEGRADATION
    BORNEMAN, WS
    HARTLEY, RD
    MORRISON, WH
    AKIN, DE
    LJUNGDAHL, LG
    [J]. APPLIED MICROBIOLOGY AND BIOTECHNOLOGY, 1990, 33 (03) : 345 - 351
  • [3] Enzymatic esterifications of functionalized phenols for the synthesis of lipophilic antioxidants
    Buisman, GJH
    van Helteren, CTW
    Kramer, GFH
    Veldsink, JW
    Derksen, JTP
    Cuperus, FP
    [J]. BIOTECHNOLOGY LETTERS, 1998, 20 (02) : 131 - 136
  • [4] PEROXYL AND HYDROXYL RADICAL SCAVENGING ACTIVITY OF SOME NATURAL PHENOLIC ANTIOXIDANTS
    CHIMI, H
    CILLARD, J
    CILLARD, P
    RAHMANI, M
    [J]. JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1991, 68 (05) : 307 - 312
  • [5] ANTIOXIDANT POTENTIAL OF FERULIC ACID
    GRAF, E
    [J]. FREE RADICAL BIOLOGY AND MEDICINE, 1992, 13 (04) : 435 - 448
  • [6] A CONVENIENT METHOD FOR ENZYMATIC BENZYL-ALKYL TRANSESTERIFICATION UNDER MILD NEUTRAL CONDITIONS
    GUTMAN, AL
    SHKOLNIK, E
    SHAPIRA, M
    [J]. TETRAHEDRON, 1992, 48 (40) : 8775 - 8780
  • [7] Esterification of phenolic acids from green coffee with an immobilized lipase from Candida antarctica in solvent-free medium
    Guyot, B
    Bosquette, B
    Pina, M
    Graille, J
    [J]. BIOTECHNOLOGY LETTERS, 1997, 19 (06) : 529 - 532
  • [8] John V. T., 1991, BIOCATAL IND, P193
  • [9] ASYMMETRIC TRANSFORMATIONS CATALYZED BY ENZYMES IN ORGANIC-SOLVENTS
    KLIBANOV, AM
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 1990, 23 (04) : 114 - 120
  • [10] THE ANTIOXIDANTS OF HIGHER-PLANTS
    LARSON, RA
    [J]. PHYTOCHEMISTRY, 1988, 27 (04) : 969 - 978