Radical bulk polymerization of styrene in the presence of fullerene[60]

被引：26

作者：

Arsalani, N ^{[1
]}

Geckeler, KE ^{[1
]}

机构：

[1] UNIV TUBINGEN,FAC CHEM & PHARM,INST ORGAN CHEM,D-72076 TUBINGEN,GERMANY

来源：

FULLERENE SCIENCE AND TECHNOLOGY | 1996年 / 4卷 / 05期

关键词：

D O I：

10.1080/10641229608001151

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The polymerization of styrene in the presence of fullerene[60] using AlBN as the initiator as well as under thermal polymerization conditions was investigated. The results indicate that the polymer yields decrease with an increase of the amount of fullerene present during the initiated and thermal polymerization. Thus, an inhibitory effect of fullerene[60] on the radical polymerization of styrene can be concluded. In addition, a mechanism for the free radical polymerization of vinyl monomers in the presence of C-60 is proposed.

引用

页码：897 / 912

页数：16

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