(Salen)Co(II) complex - an efficient catalyst for the high-pressure Friedel-Crafts reaction of 2-methylfuran with alkyl glyoxylates

被引：17

作者：

Kwiatkowski, P

Wojaczynska, E

Jurczak, J

机构：

[1] Polish Acad Sci, Inst Organ Chem, PL-01224 Warsaw, Poland

[2] Univ Warsaw, Dept Chem, PL-02093 Warsaw, Poland

[3] Wroclaw Tech Univ, Inst Organ Chem Biochem & Biotechnol, PL-50370 Wroclaw, Poland

来源：

TETRAHEDRON-ASYMMETRY | 2003年 / 14卷 / 23期

关键词：

D O I：

10.1016/j.tetasy.2003.08.012

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The high-pressure (10 kbar) reaction of 2-methylfuran I with alkyl glyoxylates 2, catalyzed by the chiral (Salen)Co(II) complex 4, afforded the Friedel-Crafts products 3 both in good yield (up to 70%) and enantio selectivity (up to 76% ee). (C) 2003 Elsevier Ltd. All rights reserved.

引用

页码：3643 / 3645

页数：3

共 10 条

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