Chiral Lewis acid-catalyzed highly enantioselective [4+3] cycloaddition reactions of nitrogen-stabilized oxyallyl cations derived from allenamides

被引：138

作者：

Huang, J ^{[1
]}

Hsung, RP ^{[1
]}

机构：

[1] Univ Minnesota, Dept Chem, Minneapolis, MN 55455 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 01期

关键词：

D O I：

10.1021/ja044760b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A chiral Lewis acid-catalyzed highly enantioselective [4 + 3] cycloaddition reaction of allenamide-derived nitrogen-stabilized chiral oxyallyl cations is described here. The use of bisoxazoline ligand and CuOTf2 provides high enantioselectivity, especially with [SbF6]- as the counteranion. Copyright © 2005 American Chemical Society.

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页码：50 / 51

页数：2

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