Formation of metal-oxygen chain structures by bridging dichromate and coordination compounds:: [MLnCr2O7]∞ (MLn=Cu2+(bipy), Ni2+(en)2, and Ni2+(bipy)2)

被引：12

作者：

Hayashi, Y ^{[1
]}

Mano, H ^{[1
]}

Uehara, A ^{[1
]}

机构：

[1] Kanazawa Univ, Fac Sci, Dept Chem, Kanazawa, Ishikawa 9201192, Japan

来源：

CHEMISTRY LETTERS | 1998年 / 09期

关键词：

D O I：

10.1246/cl.1998.899

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Metal-oxygen linear chain compounds, [Cu(bipy)Cr2O7](infinity) (1) (bipy = 2,2'-bipyridine), [Ni(en)(2)Cr2O2](infinity) (2) (en = ethylenediamine), and [{Ni(bipy)(2)Cr2O7}(CH3CN)](infinity) (3) have been prepared and characterized. X-ray structural analyses of 1 to 3 revealed three chain structures: parallel in 1, layers of chains which criss-cross in 2, and helical in 3.

引用

页码：899 / 900

页数：2

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