A thiazyl-based organic ferromagnet

被引：120

作者：

Alberola, A

Less, RJ

Pask, CM

Rawson, JM

Palacio, F

Oliete, P

Paulsen, C

Yamaguchi, A

Farley, RD

Murphy, DM

机构：

[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

[2] Univ Zaragoza, CSIC, Inst Ciencia Mat Aragon, Zaragoza 50009, Spain

[3] CNRS, CRTBT, F-38042 Grenoble 9, France

[4] Cardiff Univ, Dept Chem, Cardiff CF10 3TB, S Glam, Wales

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 39期

关键词：

ferromagnetism; magnetic properties; molecular magnetism; radical ions; radicals;

D O I：

10.1002/anie.200352194

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The sulfur-nitrogen radical p-O2NC6F 4CNSSN. (see packing diagram) provides a rare example of an organic radical that orders ferromagnetically above 1 K. It is suggested that the near orthogonal nature of the singly occupied molecular orbitals of neighboring molecules is important for such behavior to be observed.

引用

页码：4782 / 4785

页数：4

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