Cooperative THF ring-opening by B(C6F5)3 and a tellurium diimide dimer

被引：21

作者：

Chivers, T ^{[1
]}

Schatte, G ^{[1
]}

机构：

[1] Univ Calgary, Dept Chem, Calgary, AB T2N 1N4, Canada

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2003年 / 18期

关键词：

N ligands; ring opening; Lewis acids; boron; tellurium;

D O I：

10.1002/ejic.200300344

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The tellurium diimide dimer [tBuNTe(mu-NtBU)(2)TeNtBu] (1) and B(C6F5)(3) form a 1:1 adduct which instigates THF ring-opening to give [tBuNTe(mu-NtBU)(2)TeN(tBu)(CH2)(4)OB(C6F5)(3)] (3) quantitatively; complex 3 is also formed rapidly when I is added to a THF solution of B(C6F5)(3).

引用

收藏

页码：3314 / 3317

页数：4

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