Preparing water-dispersed palladium nanoparticles via polyelectrolyte nanoreactors

被引：25

作者：

Coulter, Matthew M. ^{[2
]}

Dinglasan, Jose Amado ^{[1
]}

Goh, Jane B. ^{[1
,2
]}

Nair, Sreekumari ^{[1
]}

Anderson, Darren J. ^{[1
]}

Dong, Vy M. ^{[2
]}

机构：

[1] Vive Nano Inc, Toronto, ON, Canada

[2] Univ Toronto, Dept Chem, Toronto, ON M5S 1A1, Canada

来源：

CHEMICAL SCIENCE | 2010年 / 1卷 / 06期

基金：

加拿大自然科学与工程研究理事会; 加拿大创新基金会;

关键词：

COUPLING REACTIONS; COLLOIDAL PLATINUM; HYDROGENATION; CONFORMATION; HECK; CATALYSTS; CHAINS;

D O I：

10.1039/c0sc00314j

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

A counterion-induced polyelectrolyte collapse strategy has been developed for the preparation of poly(acrylic acid) stabilized palladium nanoparticles (NP-Pd-PAA). The structure and composition of the nanoparticles were investigated via transmission electron microscopy, dynamic light scattering, powder X-ray diffraction, and X-ray photoelectron spectroscopy. NP-Pd-PAA catalyzed fully aqueous Suzuki coupling reactions at loadings as low as 0.01 mol% Pd.

引用

页码：772 / 775

页数：4

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