Solvent effect in a "solvent free" reaction

被引:105
作者
Braga, Dario
Giaffreda, Stefano Luca
Grepioni, Fabrizia
Chierotti, Michele R.
Gobetto, Roberto
Palladino, Giuseppe
Polito, Marco
机构
[1] Univ Bologna, Dipartimento Chim G Ciamician, I-40126 Bologna, Italy
[2] PolyCrystalLine SRL, I-40138 Bologna, Italy
[3] Univ Turin, IFM, Dipatimento Chim, I-10125 Turin, Italy
来源
CRYSTENGCOMM | 2007年 / 9卷 / 10期
关键词
D O I
10.1039/b711983f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Vapour digestion of a mixture of solid [Fe(eta(5)-C5H4-C5H4N)(2)] and solid pimelic acid HOOC(CH2)(5)COOH in the presence of solvent vapours generates co-crystals of different stoichiometry depending on the protic or aprotic nature of the solvent. The nature of the products has been ascertained by a combined use of SSNMR and X-ray diffraction.
引用
收藏
页码:879 / 881
页数:3
相关论文
共 50 条
[1]   Crystal engineering of the composition of pharmaceutical phases.: Do pharmaceutical co-crystals represent a new path to improved medicines? [J].
Almarsson, Ö ;
Zaworotko, MJ .
CHEMICAL COMMUNICATIONS, 2004, (17) :1889-1896
[2]   MECHANOCHEMISTRY AND MECHANICAL ACTIVATION OF SOLIDS [J].
BOLDYREV, VV .
SOLID STATE IONICS, 1993, 63-5 :537-543
[3]   Mechanochemical and solution reactions between AgCH3COO and [H2NC6H10NH2] yield three isomers of the coordination network {Ag[H2NC6H10NH2]+}∞ [J].
Braga, D ;
Curzi, M ;
Grepioni, F ;
Polito, M .
CHEMICAL COMMUNICATIONS, 2005, (23) :2915-2917
[4]   Mechanochemical preparation of molecular and supramolecular organometallic materials and coordination networks [J].
Braga, D ;
Giaffreda, SL ;
Grepioni, F ;
Pettersen, A ;
Maini, L ;
Curzi, M ;
Polito, M .
DALTON TRANSACTIONS, 2006, 6 (10) :1249-1263
[5]   Simple and quantitative mechanochemical preparation of a porous crystalline material based on a 1D coordination network for uptake of small molecules [J].
Braga, D ;
Curzi, M ;
Johansson, A ;
Polito, M ;
Rubini, K ;
Grepioni, F .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (01) :142-146
[6]   Intra-solid and inter-solid reactions of molecular crystals: a green route to crystal engineering [J].
Braga, D ;
D'Addario, D ;
Giaffreda, SL ;
Maini, L ;
Polito, M ;
Grepioni, F .
ORGANIC SOLID STATE REACTIONS, 2005, 254 :71-+
[7]   Unprecedented mechanochemical preparation of 18Crown[6] and 15Crown[5] adducts of ammonium hydrogen sulfate by grinding or kneading [J].
Braga, D ;
Curzi, M ;
Lusi, M ;
Grepioni, F .
CRYSTENGCOMM, 2005, 7 :276-278
[8]   Reactions between or within molecular crystals [J].
Braga, D ;
Grepioni, F .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (31) :4002-4011
[9]   Supramolecular complexation of alkali cations through mechanochemical reactions between crystalline solids [J].
Braga, D ;
Maini, L ;
Giaffreda, SL ;
Grepioni, F ;
Chierotti, MR ;
Gobetto, R .
CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (13) :3261-3269
[10]   Solid-state versus solution preparation of two crystal forms of [HN(CH2CH2)3NH][OOC(CH2)COOH]2.: Polymorphs or hydrogen bond isomers? [J].
Braga, D ;
Maini, L .
CHEMICAL COMMUNICATIONS, 2004, (08) :976-977