Electrode properties of Mg2Ni alloy ball-milled with cobalt powder

被引:14
作者
Chen, J [1 ]
Bradhurst, DH [1 ]
Dou, SX [1 ]
Liu, HK [1 ]
机构
[1] Univ Wollongong, Inst Supercond & Elect Mat, Wollongong, NSW 2522, Australia
关键词
Mg2Ni alloy; ball-milling; metal hydride electrode; discharge properties;
D O I
10.1016/S0013-4686(98)00167-4
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Mg2Ni alloy prepared by induction was ball-milled with 3 wt% metallic cobalt powder. The effect of the ball-milling on the alloy structure and surface image aias examined by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The mixed alloy powders before and after ball-milling were pressed on to a porous nickel foam as the active material of a metal hydride electrode. Electrochemical characteristics of the two kinds of electrodes were investigated at 25 degrees. The discharge capacity, cycle life and high-rate discharge ability showed that the electrode properties were improved greatly by the ball-milling of Mg2Ni and Co powder because of the changed structure and surface of the alloy. (C) 1998 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:353 / 355
页数:3
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