Isolation and X-ray crystal structure of an unusual biscarbene metal complex and its reactivity toward cyclopropanation and allylic C-H insertion of unfunctionalized alkenes

被引：101

作者：

Li, Y

Huang, JS

Zhou, ZY

Che, CM

机构：

[1] Univ Hong Kong, Dept Chem, Hong Kong, Hong Kong, Peoples R China

[2] Hong Kong Polytech Univ, Dept Appl Biol & Chem Technol, Kowloon, Hong Kong, Peoples R China

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2001年 / 123卷 / 20期

关键词：

D O I：

10.1021/ja003184q

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：4843 / 4844

页数：2

共 52 条

[1] CARBENE COMPLEXES .21. SYNTHESIS AND CHARACTERIZATION OF BIS(CARBENE)MOLYBDENUM(II) COMPLEXES AND DIMETAL(O) COMPLEXES OF THE GROUP-6 ELEMENTS CONTAINING NOVEL BRIDGING BIS(CARBENE) LIGANDS - X-RAY STRUCTURES OF [MO(CO)2(LET)2(OSO2CF3)2][LET = =CN(ET)(CH2)2NET] AND [W(CO)5(C(OET)CH2C6H4CH2C(OET)-O)W(CO)5]L [J].

ANDERSON, DM ;

BRISTOW, GS ;

HITCHCOCK, PB ;

JASIM, HA ;

LAPPERT, MF ;

SKELTON, BW .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1987, (11) :2843-2851

[2] PORPHYRINS .39. AMMINE AND NITRIDOOSMIUM PORPHYRINS - LIGAND EFFECTS ON THE ELECTRONIC-STRUCTURE OF OSMIUM OCTAETHYLPORPHYRINS [J].

ANTIPAS, A ;

BUCHLER, JW ;

GOUTERMAN, M ;

SMITH, PD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (01) :198-207

[3] HOMOLEPTIC CARBENE SILVER(I) AND CARBENE COPPER(I) COMPLEXES [J].

ARDUENGO, AJ ;

DIAS, HVR ;

CALABRESE, JC ;

DAVIDSON, F .

ORGANOMETALLICS, 1993, 12 (09) :3405-3409

[4] Synthesis, characterisation and reactivity of novel bis(tosyl)imidoruthenium(VI) porphyrin complexes; X-ray crystal structure of a tosylamidoruthenium(IV) porphyrin [J].

Au, SM ;

Fung, WH ;

Cheng, MC ;

Che, CM ;

Peng, SM .

CHEMICAL COMMUNICATIONS, 1997, (17) :1655-1656

[5] Aziridination of alkenes and amidation of alkanes by bis(tosylimido)ruthenium(VI) porphyrins. A mechanistic study [J].

Au, SM ;

Huang, JS ;

Yu, WY ;

Fung, WH ;

Che, CM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (39) :9120-9132

[6] HOMOLOGATION OF N-ALKANES USING DIAZOESTERS AND RHODIUM(III)PORPHYRINS - ENHANCED ATTACK ON PRIMARY C-H BONDS [J].

CALLOT, HJ ;

METZ, F .

TETRAHEDRON LETTERS, 1982, 23 (42) :4321-4324

[7] CYCLOPROPANATION USING RHODIUM(III)PORPHYRINS - LARGE CIS VS TRANS SELECTIVITY [J].

CALLOT, HJ ;

PIECHOCKI, C .

TETRAHEDRON LETTERS, 1980, 21 (36) :3489-3492

[8]

Caló V, 2000, EUR J ORG CHEM, V2000, P869

[9] EVIDENCE FOR AN ALMOST T-SHAPED COORDINATION GEOMETRY FOR CARBON IN BIS-(ALKYLIDENE) COMPLEX "TA(=CH.CME3)2(2,4,6-ME3C6H2)(PME3)2 - X-RAY CRYSTAL-STRUCTURE [J].

CHURCHILL, MR ;

YOUNGS, WJ .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1978, (23) :1048-1049

[10] CRYSTAL-STRUCTURE AND MOLECULAR-GEOMETRY OF TA(=CHCME3)2(MESITYL)(PME3)2, A BIS(ALKYLIDENE) COMPLEX OF TANTALUM WITH REMARKABLY OBTUSE TA=C(ALPHA)-C(BETA) ANGLES OF 154.0 (6) AND 168.9 (6)-DEGREES [J].

CHURCHILL, MR ;

YOUNGS, WJ .

INORGANIC CHEMISTRY, 1979, 18 (07) :1930-1935

← 1 2 3 4 5 6 →