Chemical shift of meso-carbon:: a powerful probe to determine the coordination structure and electron configuration of ferric porphyrin complexes

被引:8
作者
Nakamura, M [1 ]
Hoshino, A
Ikezaki, A
Ikeue, T
机构
[1] Toho Univ, Sch Med, Dept Chem, Ota Ku, Tokyo 1438540, Japan
[2] Toho Univ, Grad Sch Sci, Div Biomol Sci, Funabashi, Chiba 2748510, Japan
关键词
D O I
10.1039/b303785a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The meso-C-13 chemical shifts have been revealed to serve a powerful probe to determine the coordination structure and electron configuration of ferric porphyrin complexes.
引用
收藏
页码:1862 / 1863
页数:2
相关论文
共 19 条
[1]  
[Anonymous], PORPHYRIN HDB
[2]   H-1-NMR STUDY OF HIGH-SPIN FERRIC NATURAL PORPHYRIN DERIVATIVES AS MODELS OF METHEMOPROTEINS [J].
BUDD, DL ;
LAMAR, GN ;
LANGRY, KC ;
SMITH, KM ;
NAYYIRMAZHIR, R .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (20) :6091-6096
[3]   Oxidation of heme to β- and δ-biliverdin by Pseudomonas aeruginosa heme oxygenase as a consequence of an unusual seating of the heme [J].
Caignan, GA ;
Deshmukh, R ;
Wilks, A ;
Zeng, YH ;
Huang, HW ;
Moënne-Loccoz, P ;
Bunce, RA ;
Eastman, MA ;
Rivera, M .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (50) :14879-14892
[4]   Formation of pure intermediate spin complexes in highly nonplanar iron(III) porphyrins [J].
Ikeue, T ;
Saitoh, T ;
Yamaguchi, T ;
Ohgo, Y ;
Nakamura, M ;
Takahashi, M ;
Takeda, M .
CHEMICAL COMMUNICATIONS, 2000, (20) :1989-1990
[5]   Spin distribution in low-spin (meso-tetraalkylporphyrinato)iron(III) complexes with (dxz,dyz)4(dxy)1 configuration.: Studies by 1H NMR, 13C NMR, and EPR spectroscopies [J].
Ikeue, T ;
Ohgo, Y ;
Saitoh, T ;
Nakamura, M ;
Fujii, H ;
Yokoyama, M .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (17) :4068-4076
[6]  
Ikeue T, 2001, ANGEW CHEM INT EDIT, V40, P2617, DOI 10.1002/1521-3773(20010716)40:14<2617::AID-ANIE2617>3.0.CO
[7]  
2-B
[8]   Factors affecting the electronic ground state of low-spin iron(III) porphyrin complexes [J].
Ikeue, T ;
Ohgo, Y ;
Saitoh, T ;
Yamaguchi, T ;
Nakamura, M .
INORGANIC CHEMISTRY, 2001, 40 (14) :3423-3434
[9]  
La Mar G. N., 1979, PORPHYRINS B, VIVB, P57
[10]  
La Mar G. N., 2000, PORPHYRIN HDB, P185