Activation of glycosyl phosphates by in situ conversion to glycosyl iodides under neutral conditions in concentrated solutions of lithium perchlorate in organic solvents

被引：30

作者：

Schmid, U ^{[1
]}

Waldmann, H ^{[1
]}

机构：

[1] UNIV KARLSRUHE, INST ORGAN CHEM, D-76128 KARLSRUHE, GERMANY

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 22期

关键词：

D O I：

10.1016/0040-4039(96)00729-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Glycosyl phosphates are converted in situ into glycosyl iodides and thereby advantageously employed as glycosyl donors under mild neutral conditions by treatment with LiI in 1M solutions of LiClO4 in organic solvents. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：3837 / 3840

页数：4

共 29 条

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[10] USE OF 2,3,4,6-TETRA-ORTHO-BENZYL-ALPHA-D-GLYCOPYRANOSYL IODIDES IN ALPHA-GLYCOSIDE SYNTHESIS
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