Visible light induced ring-opening metathesis polymerisation of cyclooctene

被引:116
作者
Delaude, L [1 ]
Demonceau, A [1 ]
Noels, AF [1 ]
机构
[1] Univ Liege, Inst Chim B6A, CERM, B-4000 Liege, Belgium
关键词
D O I
10.1039/b101699g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Under visible light irradiation, ruthenium-arene complexes bearing N-heterocyclic carbene ligands with aryl substituents - either preformed or generated in situ - are active catalyst precursors for the ROMP of cyclooctene already at room temperature.
引用
收藏
页码:986 / 987
页数:2
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共 20 条
  • [1] Imidazolylidenes, imidazolinylidenes and imidazolidines
    Arduengo, AJ
    Krafczyk, R
    Schmutzler, R
    Craig, HA
    Goerlich, JR
    Marshall, WJ
    Unverzagt, M
    [J]. TETRAHEDRON, 1999, 55 (51) : 14523 - 14534
  • [2] ELECTRONIC STABILIZATION OF NUCLEOPHILIC CARBENES
    ARDUENGO, AJ
    DIAS, HVR
    HARLOW, RL
    KLINE, M
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (14) : 5530 - 5534
  • [3] An air stable carbene and mixed carbene "dimers"
    Arduengo, AJ
    Davidson, F
    Dias, HVR
    Goerlich, JR
    Khasnis, D
    Marshall, WJ
    Prakasha, TK
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (52) : 12742 - 12749
  • [4] Bielawski CW, 2000, ANGEW CHEM INT EDIT, V39, P2903, DOI 10.1002/1521-3773(20000818)39:16<2903::AID-ANIE2903>3.0.CO
  • [5] 2-Q
  • [6] DEMONCEAU A, 1997, MACROMOLECULES, V30, P2127
  • [7] A most user-friendly protocol for ring closing metathesis reactions
    Fürstner, A
    Ackermann, L
    [J]. CHEMICAL COMMUNICATIONS, 1999, (01) : 95 - 96
  • [8] One-component catalysts for thermal and photoinduced ring opening metathesis polymerization
    Hafner, A
    Muhlebach, A
    vanderSchaaf, PA
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (19): : 2121 - 2124
  • [9] Heterocyclic carbenes: A high-yielding synthesis of novel, functionalized N-heterocyclic carbenes in liquid ammonia
    Herrmann, WA
    Kocher, C
    Goossen, LJ
    Artus, GRJ
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 1996, 2 (12) : 1627 - 1636
  • [10] N-heterocyclic carbenes([+]): Generation under mild conditions and formation of group 8-10 transition metal complexes relevant to catalysis
    Herrmann, WA
    Elison, M
    Fischer, J
    Kocher, C
    Artus, GRJ
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 1996, 2 (07) : 772 - 780