Toward organometallic polymers with high directionality containing bis-ortho-chelating ligands

被引：25

作者：

Back, S

Albrecht, M

Spek, AL

Rheinwald, G

Lang, H

van Koten, G

机构：

[1] Tech Univ, Inst Chem, Lehrstuhl Anorgan Chem, D-09111 Chemnitz, Germany

[2] Univ Utrecht, Debye Inst, Dept Met Mediated Synth, NL-3584 CH Utrecht, Netherlands

[3] Univ Utrecht, Bijvoet Ctr Biomol Res, Dept Crystal & Struct Chem, NL-3584 CH Utrecht, Netherlands

来源：

ORGANOMETALLICS | 2001年 / 20卷 / 05期

关键词：

D O I：

10.1021/om000636z

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The preparation and structure of the rigid rod-like platinum monoacetylide {Pt}C=C-4-C6H2I-1-(CH2NMe2)(2)-2,6) ({Pt}= [Pt(C6H3{Me2NCH2}2-2,6)]) are described. Its oxidative addition to Pd(dba)(2) yields a heterobinuclear {P}C=C{Pd}I complex ({Pd}=[Pd(-4-C6H2{Me2NCH2}(2)-2, 6)](+)); this provides a new strategy for the controlled and stepwise construction of rigid rod-like metallopolymers.

引用

页码：1024 / 1027

页数：4

共 47 条

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