Tunable SERS in Gold Nanorod Dimers through Strain Control on an Elastomeric Substrate

被引:180
作者
Alexander, Kristen D. [1 ]
Skinner, Kwan [1 ]
Zhang, Shunping [2 ]
Wei, Hong [2 ]
Lopez, Rene [1 ]
机构
[1] Univ N Carolina, Dept Phys & Astron, Chapel Hill, NC 27599 USA
[2] Chinese Acad Sci, Inst Phys, Beijing Natl Lab Condensed Matter Phys, Beijing 100190, Peoples R China
关键词
Nanorod; SERS; electrodeposition; elastomer; interparticle gap; AAO template; PLASMON RESONANCES; ELECTRIC-FIELD; RAMAN; NANOSTRUCTURES; NANOPARTICLES; ENHANCEMENT; MOLECULES;
D O I
10.1021/nl1023172
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In this Letter we provide experimental verification of the interparticle distance dependence of the SERS enhancement factor in 1 mu m gold gapped nanorods. Au dimers are fabricated from electrochemically grown heterogeneous Au-Ag-Au nanorods and deposited on a stretchable elastomer film which allows active and reversible tuning of the interparticle gap on the sub-5-nm level. Significantly, this technique allows the distance dependence to be tracked using a single dimer, thereby avoiding enhancement factor reproducibility issues arising from morphological differences in disparate nanoparticle pairs.
引用
收藏
页码:4488 / 4493
页数:6
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