New bonding modes of gas-phase deposited γ-aminopropyltriethoxysilane on silica studied by 29Si CP/MAS NMR

被引:15
作者
Ek, S
Iiskola, EI
Niinistö, L
Pakkanen, TT
Root, A
机构
[1] Aalto Univ, Inorgan & Analyt Chem Lab, FIN-02015 Espoo, Finland
[2] Univ Joensuu, Dept Chem, FIN-80101 Joensuu, Finland
[3] Fortum Oil & Gas Oy, Ctr Technol, FIN-06101 Porvoo, Finland
关键词
D O I
10.1039/b305534e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Besides the well-known reaction between the ethoxy groups of the silane end of the gamma-aminopropyltriethoxysilane (APTS) molecule and the silanols of silica, the amino ends of APTS molecules were observed to react in the gas phase with ethoxy groups of other APTS molecules and silanols of silica at elevated temperatures on the silica surface, dehydroxylated at 600 degreesC, forming Si-N linkages, as established by Si-29 CP/MAS NMR.
引用
收藏
页码:2032 / 2033
页数:2
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