Highly stable metal hydrous oxide colloids by inorganic polycondensation in suspension

被引：51

作者：

Gérardin, C

Sanson, N

Bouyer, F

Fajula, F

Putaux, JL

Joanicot, M

Chopin, T

机构：

[1] CNRS, UMR 5618 ENSCM, Lab Mat Catalyt & Catalyse Chim Organ, F-34296 Montpellier 5, France

[2] Univ Grenoble 1, Ctr Rech Macromol Vegetales, CNRS, Grenoble, France

[3] Rhodia Inc, Rhodia Complex Fluids Lab, CNRS, Cranbury, NJ 08512 USA

[4] Rhone Poulenc Rech, Ctr Aubervilliers, F-93308 Aubervilliers, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 31期

关键词：

block copolymers; colloids; metal hydroxides; micelles; nanostructures;

D O I：

10.1002/anie.200350917

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hybrid core-corona nanoassemblies (shown schematically in the picture, middle) can be used as supramolecular precursors for metal hydroxide colloids (right) with long-term stability. Anionic-neutral hydrophilic diblock copolymers allow metal hydrolysis and condensation reactions to occur in suspension. Particle size and morphology can be varied by adjusting the degree of metal complexation.

引用

页码：3681 / 3685

页数：5

共 36 条

[1]

Allouche L, 2000, ANGEW CHEM INT EDIT, V39, P511, DOI 10.1002/(SICI)1521-3773(20000204)39:3<511::AID-ANIE511>3.0.CO

[2]

2-N

[3]

ANTONIETTI M, 1992, NACHR CHEM TECH LAB, V40, P308

[4] Induced micellization by interaction of poly(2-vinylpyridine)-block-poly(ethylene oxide) with metal compounds.: Micelle characteristics and metal nanoparticle formation [J].

Bronstein, LH ;

Sidorov, SN ;

Valetsky, PM ;

Hartmann, J ;

Cölfen, H ;

Antonietti, M .

LANGMUIR, 1999, 15 (19) :6256-6262

[5]

Cölfen H, 2001, MACROMOL RAPID COMM, V22, P219, DOI 10.1002/1521-3927(20010201)22:4<219::AID-MARC219>3.0.CO

[6]

2-G

[7] Crystal design of calcium carbonate microparticles using double-hydrophilic block copolymers [J].

Colfen, H ;

Antonietti, M .

LANGMUIR, 1998, 14 (03) :582-589

[8]

Forster S, 1998, ADV MATER, V10, P195, DOI 10.1002/(SICI)1521-4095(199802)10:3<195::AID-ADMA195>3.0.CO

[9]

2-V

[10]

Göltner C, 2001, SURF SCI SERIES, V100, P797

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