Metal-mediated Barbier-type carbonyl allylation under solvent-free conditions

被引：32

作者：

Yi, XH ^{[1
]}

Haberman, JX ^{[1
]}

Li, CJ ^{[1
]}

机构：

[1] Tulane Univ, Dept Chem, New Orleans, LA 70118 USA

来源：

SYNTHETIC COMMUNICATIONS | 1998年 / 28卷 / 16期

关键词：

D O I：

10.1080/00397919808004878

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Zinc, tin, and indium mediated Barbier-type cross coupling between carbonyl compounds and allyl halides have been investigated without additional solvent. The indium mediated reactions proceed effectively under solvent free conditions. To a more limited extent, the reactions were found to be mediated by zinc and tin. Various carbonyl compounds are transformed into the corresponding allylation product in this way. No apparent competing pinacol-coupling or home-coupling of the allyl halide was observed.

引用

页码：2999 / 3009

页数：11

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