Predictable and unpredictable reactions between 4,4′-dipyridyldisulfide and phosphonodithioato/dithiophosphato NiII complexes:: novel coordination polymers and the unique example of 4,4′-dipyridyltrisulfide

被引：51

作者：

Aragoni, M. Carla

Arca, Massimiliano

Crespo, Miriam

Devillanova, Francesco A.

Hursthouse, Michael B.

Huth, Susanne L.

Isaia, Francesco

Lippolis, Vito

Verani, Gaetano

机构：

[1] Univ Cagliari, Dipartimento Chim Inorgan & Anal, I-09042 Cagliari, Italy

[2] Univ Southampton, Sch Chem, Southampton SO17 1BJ, Hants, England

来源：

CRYSTENGCOMM | 2007年 / 9卷 / 10期

关键词：

D O I：

10.1039/b708972d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reactions between dpds and the phosphonodithioato and dithiophosphato Ni-II complexes [Ni(MeOpdt)(2)] (1), [Ni(EtOpdt)(2)] (2), and [Ni((EtO)(2)PS2)(2)] (3) yielded the novel coordination polymers (1.dpds)(infinity), (2.dpts)(infinity), and (3.dps)(infinity), featuring three different spacers ensuing from in situ chemical rearrangement of the starting dpds reagent (dpds, 4,4 '-dipyridyldisulfide; dps, 4,4 '-dipyridylmonosulfide; dpts, 4,4 '-dipyridyltrisulfide).

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收藏

页码：873 / 878

页数：6

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