Nuclear resonant scattering and molecular orbital calculations on an iron(II) spin-crossover complex

被引：18

作者：

Grunsteudel, H ^{[1
]}

Paulsen, H

Meyer-Klaucke, W

Winkler, H

Trautwein, AX

Grunsteudel, HF

Baron, AQR

Chumakov, AI

Ruffer, R

Toftlund, H

机构：

[1] Univ Lubeck, Inst Phys, D-23538 Lubeck, Germany

[2] European Synchrotron Radiat Facil, Nucl Resonance Grp, F-38043 Grenoble, France

[3] Odense Univ, Dept Chem, DK-5230 Odense M, Denmark

来源：

HYPERFINE INTERACTIONS | 1998年 / 113卷 / 1-4期

关键词：

D O I：

10.1023/A:1012641614937

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

Nuclear resonant scattering of synchrotron radiation was applied to investigate the spin-crossover complex Fe(tpa)(NCS)(2) (tpa = tris(2-pyridylmethyl)amine). The nuclear forward scattering experiments are compared with conventional Mossbauer experiments, and the nuclear inelastic scattering experiments are compared with the results from a theoretical normal mode analysis based on molecular orbital calculations.

引用

页码：311 / 317

页数：7

共 22 条

[1] DYNAMICS OF SPIN EQUILIBRIA IN METAL-COMPLEXES [J].