Thermal polymerization of arylacetylenes .2. Study of linear dimers

被引：12

作者：

Gandon, S ^{[1
]}

Mison, P ^{[1
]}

Sillion, B ^{[1
]}

机构：

[1] IFP,CNRS,UMR 102,F-69390 VERNAISON,FRANCE

来源：

POLYMER | 1997年 / 38卷 / 06期

关键词：

thermal polymerization; diyne; enynes;

D O I：

10.1016/S0032-3861(97)89718-2

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Four linear dimers of 4-(hexyloxy)phenylacetylene I have been synthesized and thermally polymerized under the same conditions which were used for I. The polymerization of monomer and linear dimer mixtures was also studied. The reaction products were analysed by chromatography, spectroscopy and spectrometry techniques. The experimental results led us to conclude that the linear dimers are not reaction intermediates of the thermal polymerization of I. (C) 1997 Elsevier Science Ltd.

引用

页码：1449 / 1459

页数：11

共 16 条

[1] SUBSTITUTIONS- UND ADDITIONSREAKTIONEN AN SILYLIERTEN ACETYLENEN
BIRKOFER, L
UHLENBRA.H
RITTER, A
[J]. CHEMISCHE BERICHTE-RECUEIL, 1963, 96 (12): : 3280 - &
[2] BRANDSMA L, 1988, STUDIES ORGANIC CHEM, V34, P284
[3] FRITZSCHE V, 1972, TETRAHEDRON LETT, P4831
[4] Thermal polymerization of arylacetylenes .1. Study of a monofunctional model compound
Gandon, S
Mison, P
Bartholin, M
Mercier, R
Sillion, B
[J]. POLYMER, 1997, 38 (06) : 1439 - 1447
[5] GANDON S, UNPUB POLYMER
[6] Glaser C, 1869, CHEM GES, V2, P422
[7] DIACETYLENIC LIQUID-CRYSTALS - SYNTHESIS AND PRELIMINARY CHARACTERIZATION OF 4,4'-DIALKYL AND 4,4'-DIALKOXY DERIVATIVES OF DIPHENYLDIACETYLENE
GRANT, B
[J]. MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1978, 48 (3-4): : 175 - 182
[8] Grenier-Loustalot M.-.F., 1994, HIGH PERFORM POLYM, V6, P347
[9] Hergenrother PM, 1979, POLYM PREPR AM CHEM, V24, P243
[10] KIRILLOVA LP, 1974, J ORG CHEM USSR, P2001

← 1 2 →