Non-woody plants as raw materials for production of microfibrillated cellulose (MFC): A comparative study

被引:159
作者
Alila, Sabrine [1 ]
Besbes, Iskander [1 ]
Vilar, Manuel Rei [2 ]
Mutje, Pere [3 ]
Boufi, Sami [1 ]
机构
[1] Univ Sfax, Fac Sci Sfax, Lab Sci Mat & Environm, Sfax, Tunisia
[2] Univ Paris Diderot, CNR UMR7086, ITODYS, Paris, France
[3] Univ Girona, LEPAMAP Grp, Girona 17071, Spain
关键词
Microfibrillated cellulose (MFC); Non-woody plants; Homogenization; NANOFIBERS; OXIDATION; FIBERS; ALPHA; KENAF;
D O I
10.1016/j.indcrop.2012.04.028
中图分类号
S2 [农业工程];
学科分类号
0828 ;
摘要
The extraction of microfibrillated cellulose (MFC) from fibres of several non-woody plants (basts of flax, hemp, jute, leaves of sisal and abaca) has been explored. MFC was isolated using high pressure homogenization process at a pressure lower than 600 bar. Fibres extracted from the plants by alkaline pulping process were first bleached and submitted to TEMPO-mediated oxidation to facilitate the fibrillation process. Evidence of the successful isolation of nanofibrils was given by FE-SEM observation revealing fibrils with a width in the 20 up to 50 nm range, depending on the fibres origin. Particular attention was paid to characterize the ensuing MFC using different physical methods (DP, transparency degree, DRX) to enable a comparative analysis of the nanofibrils properties, and evaluate the ease of fibrillation. From this investigation, it seems that the fibres with the highest content in hemicelluloses led to the highest yield in MFC. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码:250 / 259
页数:10
相关论文
共 35 条
[1]   Biocomposites from wheat straw nanofibers: Morphology, thermal and mechanical properties [J].
Alemdar, Ayse ;
Sain, Mohini .
COMPOSITES SCIENCE AND TECHNOLOGY, 2008, 68 (02) :557-565
[2]   Oxygen and oil barrier properties of microfibrillated cellulose films and coatings [J].
Aulin, Christian ;
Gallstedt, Mikael ;
Lindstrom, Tom .
CELLULOSE, 2010, 17 (03) :559-574
[3]   Nanofibrillated cellulose from Alfa, Eucalyptus and Pine fibres: Preparation, characteristics and reinforcing potential [J].
Besbes, Iskander ;
Vilar, Manuel Rei ;
Boufi, Sami .
CARBOHYDRATE POLYMERS, 2011, 86 (03) :1198-1206
[4]   Nanofibrillated cellulose from TEMPO-oxidized eucalyptus fibres: Effect of the carboxyl content [J].
Besbes, Iskander ;
Alila, Sabrine ;
Boufi, Sami .
CARBOHYDRATE POLYMERS, 2011, 84 (03) :975-983
[5]   Mechanical, barrier, and biodegradability properties of bagasse cellulose whiskers reinforced natural rubber nanocomposites [J].
Bras, Julien ;
Hassan, Mohammad L. ;
Bruzesse, Cecile ;
Hassan, Enas A. ;
El-Wakil, Nahla A. ;
Dufresne, Alain .
INDUSTRIAL CROPS AND PRODUCTS, 2010, 32 (03) :627-633
[6]   Viscoelastic behavior and electrical properties of flexible nanofiber filled polymer nanocomposites.: Influence of processing conditions [J].
Dalmas, Florent ;
Cavaille, Jean-Yves ;
Gauthier, Catherine ;
Chazeau, Laurent ;
Dendievel, Remy .
COMPOSITES SCIENCE AND TECHNOLOGY, 2007, 67 (05) :829-839
[7]   The use of microfibrillated cellulose produced from kraft pulp as strength enhancer in TMP paper [J].
Eriksen, Oyvind ;
Syverud, Kristin ;
Gregersen, Oyvind .
NORDIC PULP & PAPER RESEARCH JOURNAL, 2008, 23 (03) :299-304
[8]   Nanofibers from bagasse and rice straw: process optimization and properties [J].
Hassan, Mohammad L. ;
Mathew, Aji P. ;
Hassan, Enas A. ;
El-Wakil, Nahla A. ;
Oksman, Kristiina .
WOOD SCIENCE AND TECHNOLOGY, 2012, 46 (1-3) :193-205
[9]   An environmentally friendly method for enzyme-assisted preparation of microfibrillated cellulose (MFC) nanofibers [J].
Henriksson, M. ;
Henriksson, G. ;
Berglund, L. A. ;
Lindstrom, T. .
EUROPEAN POLYMER JOURNAL, 2007, 43 (08) :3434-3441
[10]   Nano-fibrillation of pulp fibers for the processing of transparent nanocomposites [J].
Iwamoto, S. ;
Nakagaito, A. N. ;
Yano, H. .
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2007, 89 (02) :461-466