Electrochemical characteristics of negative electrodes made of ozone-treated graphite for lithium-ion batteries

被引:4
作者
Kulova, TL
Kanevskii, LS
Skundin, AM
Sklovskii, DE
Asryan, NA
Bondarenko, GN
机构
[1] Russian Acad Sci, AN Frumkin Electrochem Inst, Moscow 117071, Russia
[2] Moscow MV Lomonosov State Univ, Moscow 119899, Russia
[3] Russian Acad Sci, AV Topchiev Petrochem Synth Inst, Moscow 117912, Russia
关键词
D O I
10.1023/A:1012306710594
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Electrochemical characteristics of negative electrodes made of graphite treated in ozone-oxygen environment are studied in an operating lithium-ion battery. Successively treating graphite with ozone and then with a sec-butyllithium solution in cyclohexane dramatically reduces the irreversible capacity and stabilizes discharge characteristics of graphite electrodes cycled in a propylene carbonate-based electrolyte. An ozone-oxygen gaseous mixture containing 5 vol % O-3 is Most effective for the stabilization. According to IR spectroscopy, the treatment gives rise largely to -COLi groups, which ex situ form a passivating solid-electrolyte film on the graphite surface. The film hampers the electroreduction of the organic solvent and reduces the irreversible lithium consumption.
引用
收藏
页码:1017 / 1023
页数:7
相关论文
共 30 条
[1]  
[Anonymous], INTERFACE
[2]   THE CATHODIC DECOMPOSITION OF PROPYLENE CARBONATE IN LITHIUM BATTERIES [J].
ARAKAWA, M ;
YAMAKI, JI .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1987, 219 (1-2) :273-280
[3]  
ATYAKSHEVA LF, 1983, VESTN MOSK U KHIM+, V24, P462
[4]   Recent developments on lithium ion batteries at SAFT [J].
Broussely, M .
JOURNAL OF POWER SOURCES, 1999, 81 :140-143
[5]  
CHUSID O, 1993, J POWER SOURCES, V43, P47, DOI 10.1016/0378-7753(93)80101-T
[6]   RECHARGEABLE LINIO2 CARBON CELLS [J].
DAHN, JR ;
VONSACKEN, U ;
JUZKOW, MW ;
ALJANABY, H .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1991, 138 (08) :2207-2211
[7]   Chemical oxidation: A route to enhanced capacity in Li-ion graphite anodes [J].
EinEli, Y ;
Koch, VR .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1997, 144 (09) :2968-2973
[8]   STUDIES OF LITHIUM INTERCALATION INTO CARBONS USING NONAQUEOUS ELECTROCHEMICAL-CELLS [J].
FONG, R ;
VONSACKEN, U ;
DAHN, JR .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1990, 137 (07) :2009-2013
[9]   A new structural model for graphite oxide [J].
He, HY ;
Klinowski, J ;
Forster, M ;
Lerf, A .
CHEMICAL PHYSICS LETTERS, 1998, 287 (1-2) :53-56
[10]  
IIJIMA M, 1990, P 31 BATT S OS, P273