Chiral discrimination in cycloaddition experiments

被引：16

作者：

Borm, C ^{[1
]}

Meibom, D ^{[1
]}

Winterfeldt, E ^{[1
]}

机构：

[1] UNIV HANNOVER,INST ORGAN CHEM,D-30167 HANNOVER,GERMANY

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 08期

关键词：

D O I：

10.1039/cc9960000887

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Various applications of a chiral cyclopentadiene in chiral recognition experiments are reported. Racemic cyelic dienophiles undergo very efficient kinetic resolution while with prochiral cyclohexadienones discrimination of enantiotopic groups is observed. In one particular case a racemic exo-methylene lactone from to a highly stereospecific cycloaddition yielded to topographic resolution.

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收藏

页码：887 / 894

页数：8

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