(+)(589)-Lambda-Amminebromobis(ethylenediamine-N,N')cobalt(III) dibromide

被引:11
作者
Nakagawa, H [1 ]
Ohba, S [1 ]
Asakura, K [1 ]
Miura, T [1 ]
Tanaka, A [1 ]
Osanai, S [1 ]
机构
[1] KEIO UNIV,FAC SCI & TECHNOL,DEPT APPL CHEM,KOHOKU KU,YOKOHAMA,KANAGAWA 223,JAPAN
关键词
D O I
10.1107/S0108270196013479
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The absolute configuration of (+)(589)-cis-[CoBr(C2H8N2)(2)(NH3)](2+) was confirmed to be Lambda. The ethylenediamine five-membered chelate rings take the lel(2) conformation. There are N-H ... Br intermolecular hydrogen bonds with N ... Br distances ranging from 3.267(9) to 3.715 (8) Angstrom.
引用
收藏
页码:216 / 217
页数:2
相关论文
共 6 条
[1]   GENERATION OF AN OPTICALLY-ACTIVE OCTAHEDRAL COBALT COMPLEX BY A CHIRAL AUTOCATALYSIS [J].
ASAKURA, K ;
KOBAYASHI, K ;
MIZUSAWA, Y ;
OZAWA, T ;
OSANAI, S ;
YOSHIKAWA, S .
PHYSICA D, 1995, 84 (1-2) :72-78
[2]   THE PHENOMENON OF CONGLOMERATE CRYSTALLIZATION .25. SPONTANEOUS RESOLUTION IN COORDINATION-COMPOUNDS - THE CRYSTAL-STRUCTURE OF [CIS-CO(EN)2(NH3)BR]BR2 [J].
BERNAL, I ;
CETRULLO, J ;
JACKSON, WG .
JOURNAL OF COORDINATION CHEMISTRY, 1993, 28 (01) :89-95
[3]   THE PHENOMENON OF CONGLOMERATE CRYSTALLIZATION .24. SPONTANEOUS RESOLUTION IN COORDINATION-COMPOUNDS - CLASSICAL AND SPONTANEOUS RESOLUTION OF THE [CO(EN)2(NH3)BR]2+ CATION - CRYSTAL-STRUCTURES AND ABSOLUTE-CONFIGURATIONS OF RESOLVED (+)589-[CIS-LAMBDA(DELTA-LAMBDA)-CO(EN)2(NH3)BR]S4O6 (I) AND OF CONGLOMERATE CRYSTALS OF [CIS-LAMBDA-DELTA-LAMBDA)-CO(EN)2(NH3)BR]S4O6 (II) [J].
BERNAL, I ;
CETRULLO, J ;
JACKSON, WG .
INORGANIC CHEMISTRY, 1993, 32 (19) :4098-4101
[4]  
EDWARDS C, 1995, CRYSTAN GM COMPUTER
[5]   CRYSTAL-STRUCTURES OF CIS-(N-BASE)CHLOROBIS-(ETHANE-1,2-DIAMINE)COBALT(III) DICHLORIDE (N-BASE = AMMONIA, PYRIDINE) [J].
HARROWFIELD, JM ;
SKELTON, BW ;
WHITE, AH ;
WILNER, FR .
AUSTRALIAN JOURNAL OF CHEMISTRY, 1986, 39 (02) :339-346
[6]   STRUCTURAL STUDY OF OPTICAL RESOLUTION .6. CRYSTAL-STRUCTURE OF (+)589-CIS-CHLOROAMMINEBIS(ETHYLENEDIAMINE)COBALT(III) D-3-BROMOCAMPHOR-9-SULFONATE MONOHYDRATE [J].
KURAMOTO, M ;
KUSHI, Y ;
YONEDA, H .
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1978, 51 (11) :3196-3202