Electron transfer.: 149.: Reactions of hypervalent chromium with s2 metal-ion reducing centers

被引：15

作者：

Babich, OA ^{[1
]}

Gould, ES ^{[1
]}

机构：

[1] Kent State Univ, Dept Chem, Kent, OH 44242 USA

来源：

INORGANIC CHEMISTRY | 2001年 / 40卷 / 22期

关键词：

D O I：

10.1021/ic0014686

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reductions of HCrO4- with excess Ge(II), In(I), and Sn(II) give predominantly Cr(II), trapped by its rapid reaction with added (NH3)(5)CoF2+. The conversions, which involve changes of two units, pass through Cr(IV), bypassing Cr(III), and are thought to proceed by oxygen atom transfer.

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页码：5708 / +

页数：4

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