CO removal from reformed gas by catalytic methanation for polymer electrolyte fuel cell applications

被引：26

作者：

Echigo, M ^{[1
]}

Tabata, T ^{[1
]}

机构：

[1] Osaka Gas Co Ltd, Residential Cogenerat Dev Dept, Osaka 5540041, Japan

来源：

JOURNAL OF CHEMICAL ENGINEERING OF JAPAN | 2004年 / 37卷 / 01期

关键词：

CO removal; methanation; reformed gas; Ru catalyst; PEFC;

D O I：

10.1252/jcej.37.75

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

CO removal from a reformed gas by catalytic methanation on Ru/Al2O3 was studied for Polymer Electrolyte Fuel Cell (PEFC) systems. The effects of the gas composition and the reaction temperature on CO methanation activity were examined. The ratio of methanation of CO to that of CO + CO2 was also investigated. Consequently, it was found that CO could be removed from a reformed gas to below 10 ppm by controlling CO. methanation by multi-stage CO methanation, while CO could not be reduced to below 10 ppm by single-stage CO methanation due to the presence of CO2.

引用

页码：75 / 81

页数：7

共 14 条

[1]

ECHIGO M, 2003, UNPUB J CHEM ENG JAP

[2] ADSORPTION AND METHANATION OF CARBON-DIOXIDE ON A NICKEL-SILICA CATALYST [J].

FALCONER, JL ;

ZAGLI, AE .

JOURNAL OF CATALYSIS, 1980, 62 (02) :280-285

[3] A NEW APPROACH TO THE PROBLEM OF CARBON-MONOXIDE POISONING IN FUEL-CELLS OPERATING AT LOW-TEMPERATURES [J].

GOTTESFELD, S ;

PAFFORD, J .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1988, 135 (10) :2651-2652

[4]

HERWIJNEN TV, 1973, J CATAL, V28, P391

[5]

INBODY MA, 1998, 1998 FUEL CELL SEM P, P475

[6]

INBODY MA, 2000, 2000 FUEL CELL SEM P, P86

[7] FUEL-CELLS FOR TRANSPORTATION [J].

LEMONS, RA .

JOURNAL OF POWER SOURCES, 1990, 29 (1-2) :251-264

[8]

Masuda M., 1994, 1994 FUEL CELL SEM S, P380

[9]

Okada O, 2001, FUEL CELLS, V1, P72

[10]

OSHIRO H, 1996, 1996 FUEL CELL SEM O, P319

← 1 2 →