Conductivity, Viscosity, and Dissolution Enthalpy of LiNTF2 in Ionic Liquid BMINTF2

被引：40

作者：

Andriola, Angelo ^{[1
]}

Singh, Kulwinder ^{[1
]}

Lewis, James ^{[1
]}

Yu, Lei ^{[1
]}

机构：

[1] Rowan Univ, Dept Chem & Biochem, Glassboro, NJ 08028 USA

来源：

JOURNAL OF PHYSICAL CHEMISTRY B | 2010年 / 114卷 / 36期

关键词：

LITHIUM SECONDARY BATTERIES; LI/LICOO2; CELL; ELECTROLYTES; DISCHARGE; SOLVENT;

D O I：

10.1021/jp1044404

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The ionic conductivity, relative viscosity, and solution enthalpy of LiNTF2 and NaNTF2 solutions in ionic liquid BMINTF2 have been measured. We observed that the conductivity decreased and the viscosity increased when the Li+ and Na+ salts were dissolved in BMINTF2. We also observed that the dissolution is an exothermic process with a solution enthalpy of approximately -18.07 +4.61 kJ/mol. The experimental results indicate that the Li+ ion may associate with multiple NTF2- anions in the BMINTF2 solution to form a solvated complex.

引用

页码：11709 / 11714

页数：6

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