Redox behaviour of azulenyl nitrones: fully reversible one electron oxidation by cyclic voltammetry at potentials in the range of biological antioxidants

被引：13

作者：

Becker, DA ^{[1
]}

Natero, R

Echegoyen, L

Lawson, RC

机构：

[1] Florida Int Univ, Dept Chem, Miami, FL 33199 USA

[2] Univ Miami, Dept Chem, Coral Gables, FL 33124 USA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1998年 / 06期

关键词：

D O I：

10.1039/a708702k

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The one electron oxidation chemistry of azulenyl nitrones 4 and 5 employing cyclic voltammetry reveals that, unlike conventional nitrone spin traps such as PEN and S-PBN, such oxidation is electrochemically and chemically reversible at potentials near or within those of Important biological chain-breaking antioxidants.

引用

收藏

页码：1289 / 1291

页数：3

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