Recent Advances in Lanthanide-Containing Polyoxotungstates

被引：116

作者：

Bassil, Bassem S. ^{[1
]}

Kortz, Ulrich ^{[1
]}

机构：

[1] Jacobs Univ, Sch Sci & Engn, D-28725 Bremen, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2010年 / 636卷 / 12期

关键词：

Lanthanides; Tungsten; Polyoxometalates; Coordination chemistry; Solid state chemistry; CRYSTAL-STRUCTURE; STRUCTURAL-CHARACTERIZATION; HETEROPOLYTUNGSTATE ANION; POLYOXOMETALATE CHAINS; NMR-SPECTROSCOPY; BUILDING-BLOCKS; SOLID-STATE; COMPLEXES; DAWSON; P-31;

D O I：

10.1002/zaac.201000201

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The area of lanthanide-containing polyoxometalates has been a field of large interest for several years due to the interesting structural and physicochemical properties of such compounds. This chemistry is dominated by tungsten based POMs, as a large number of vacant (lacunary) polytungstate precursors is known (as opposed to vanadium or molybdenum based POMs). The main subclasses in this field are lanthanide-containing iso- and hetero-polytungstates. The number of examples in the latter class is significantly larger than the former, probably because more lacunary hetero- than iso-polytungstates are known. Here we report on recent examples of lanthanide-containing iso- and hetero-polytungstates with a focus on synthetic and in particular structural aspects. The compounds discussed include discrete molecular species as well as 1-, 2- and 3-D solid-state assemblies.

引用

页码：2222 / 2231

页数：10

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