Large-scale ozone and aerosol distributions, air mass characteristics, and ozone fluxes over the western Pacific Ocean in late winter/early spring

[1] Large-scale measurements of ozone (O-3) and aerosol distributions were made from the NASA DC-8 aircraft during the Transport and Chemical Evolution over the Pacific (TRACE-P) field experiment conducted in February-April 2001. Remote measurements were made with an airborne lidar to provide O-3 and multiple-wavelength aerosol backscatter profiles from near the surface to above the tropopause along the flight track. In situ measurements of O-3, aerosols, and a wide range of trace gases were made onboard the DC-8. Five-day backward trajectories were used in conjunction with the O-3 and aerosol distributions on each flight to indicate the possible origin of observed air masses, such as from biomass burning regions, continental pollution, desert regions, and oceanic regions. Average latitudinal O-3 and aerosol scattering ratio distributions were derived from all flights west of 150degreesE, and these distributions showed the average latitude and altitude dependence of different dynamical and chemical processes in determining the atmospheric composition over the western Pacific. TRACE-P (TP) showed an increase in the average latitudinal distributions of both O-3 and aerosols compared to PEM-West B (PWB), which was conducted in February-March 1994. O-3, aerosol, and potential vorticity levels were used to identify nine air mass types and quantify their frequency of occurrence as a function of altitude. This paper discusses the characteristics of the different air mass types encountered during TP and compares them to PWB. These results confirmed that most of the O-3 increase in TP was due to photochemistry. The average latitudinal eastward O-3 flux in the western Pacific during TP was found to peak near 32degreesN with a total average O-3 flux between 14 and 46degreesN of 5.2 Tg/day. The eastward total CO flux was calculated to be 2.2 Tg-C/day with -6% estimated from Asia. The Asian flux of CO2 and CH4 was estimated at 4.9 and 0.06 Tg-C/day.