Characterization of photochemically converted poly(para-phenylene vinylene)

被引：21

作者：

Wery, J

Dulieu, B

Bullot, J

Baitoul, M

Deniard, P

Buisson, JP

机构：

[1] Univ Nantes, Inst Mat Nantes, Lab Phys Cristalline, UMR 6502, F-44322 Nantes 3, France

[2] Univ Nantes, Inst Mat Nantes, Lab Chim Solides, UMR 6502, F-44322 Nantes, France

来源：

POLYMER | 1999年 / 40卷 / 02期

关键词：

UV-Vis-NIR absorption; infrared and Raman spectroscopy; X-ray diffraction;

D O I：

10.1016/S0032-3861(98)00250-X

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The assisted photochemical conversion of precursor polymer synthesized via the procedure using tetrahydrothiophenium group is studied, particularly the influence of the substrate temperature and duration of the illumination period followed by optical absorption measurements. The optimal experimental conditions are obtained for a substrate temperature T = 110 degrees C and an illumination period of at least 30 min. The characterization of the optimized photochemically converted poly(p-phenylene vinylene) [PPV] has been investigated by means of optical absorption, infrared absorption, X-ray diffraction and resonant Raman scattering spectroscopy, We find that optical and structural properties of the optimized photoconverted are rather close to those of standard PPV. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：519 / 523

页数：5

共 21 条

[1]

[Anonymous], 1991, Conjugated Polymers: The Novel Science and Technology of Highly Conducting and Nonlinear Optically Active Material

[2] PRECURSOR-ROUTE POLY(P-PHENYLENEVINYLENE) - POLYMER CHARACTERIZATION AND CONTROL OF ELECTRONIC-PROPERTIES [J].