Synthesis and structure of a new 3D porous Cu(II)-benzene-1,3,5-tricarboxylate coordination polymer, [Cu2(OH)(BTC)(H2O)]n•2nH2O

被引:48
作者
Chen, JX [1 ]
Yu, T [1 ]
Chen, ZX [1 ]
Xiao, HP [1 ]
Zhou, GQ [1 ]
Weng, LH [1 ]
Tu, B [1 ]
Zhao, DY [1 ]
机构
[1] Fudan Univ, Dept Chem, Mol Catalysis & Innovat Mat Lab, Shanghai 200433, Peoples R China
关键词
D O I
10.1246/cl.2003.590
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The reaction of Cu(NO3)(2)(.)3H(2)O with benzene-1,3,5-tricarboxylic acid (H3BTC) and H2O under hydrothermal conditions affords a new three-dimensional porous coordination polymer, [Cu-2(OH)(BTC)(H2O)](n)(.)2nH(2)O, which contains 5 x 7Angstrom dimension lozenge shaped ID open channels along the crystallo-graphic a axis.
引用
收藏
页码:590 / 591
页数:2
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