A titanium disilicide derived semiconducting catalyst for water splitting under solar radiation -: Reversible storage of oxygen and hydrogen

被引：109

作者：

Ritterskamp, Peter

Kuklya, Andriy

Wuestkamp, Marc-Andre

Kerpen, Klaus

Weidenthaler, Claudia

Demuth, Martin ^{[1
]}

机构：

[1] Max Planck Inst Bioorgan Chem, D-45413 Mulheim, Germany

[2] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 41期

关键词：

heterogeneous catalysis; photochemistry; semiconductors; surface chemistry; water splitting;

D O I：

10.1002/anie.200701626

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Divide and separate: Photocatalytic splitting of water into hydrogen and oxygen is achieved with a catalyst which is formed on the surface of titanium dicilicide (see picture). The two product gases are reversibly physisorbed by the catalyst. Desorption of hydrogen occurs at ambient temperature, but oxygen is entirely stored up to 100°C in light and can be released upon heating at this temperature in the dark, which allows convenient separation of the gases. © 2007 Wiley-VCH Verlag GmbH &. Co. KGaA.

引用

页码：7770 / 7774

页数：5

共 24 条

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[2] The future of energy supply: Challenges and opportunities [J].