On the reactivity of phosphate monoester dianions in aqueous solution:: Bronsted linear free-energy relationships do not have an unique mechanistic interpretation

被引：67

作者：

Florián, J

Aqvist, J

Warshel, A ^{[1
]}

机构：

[1] Univ So Calif, Dept Chem, Los Angeles, CA 90089 USA

[2] Uppsala Univ, Ctr Biomed, Dept Biol Mol, S-75124 Uppsala, Sweden

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1998年 / 120卷 / 44期

关键词：

D O I：

10.1021/ja982698a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：11524 / 11525

页数：2

共 16 条

[1] MAPPING THE TRANSITION-STATE FOR ATP HYDROLYSIS - IMPLICATIONS FOR ENZYMATIC CATALYSIS [J].

ADMIRAAL, SJ ;

HERSCHLAG, D .

CHEMISTRY & BIOLOGY, 1995, 2 (11) :729-739

[2]

BENKOVIC SJ, TRANSITION STATES BI

[3] MECHANISMS OF NUCLEOPHILIC SUBSTITUTION IN PHOSPHATE ESTERS [J].

COX, JR ;

RAMSAY, OB .

CHEMICAL REVIEWS, 1964, 64 (04) :317-&

[4]

Dempsey B, 1979, IONIZATION CONSTANTS, V23, P989

[5] Phosphate ester hydrolysis in aqueous solution:: Associative versus dissociative mechanisms [J].

Florián, J ;

Warshel, A .

JOURNAL OF PHYSICAL CHEMISTRY B, 1998, 102 (04) :719-734

[6] A fundamental assumption about OH- attack in phosphate ester hydrolysis is not fully justified [J].

Florian, J ;

Warshel, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (23) :5473-5474

[7]

FLORIAN J, 1997, CHEMSOL 1 0

[8] REACTIVITY OF NUCLEOPHILIC REAGENTS TOWARD P-NITROPHENYL PHOSPHATE DIANION [J].

KIRBY, AJ ;

JENCKS, WP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1965, 87 (14) :3209-&

[9] REACTIVITY OF PHOSPHATE ESTERS - REACTIONS OF MONOESTERS WITH NUCLEOPHILES . NUCLEOPHILICITY INDEPENDENT OF BASICITY IN A BIMOLECULAR SUBSSTITUTION REACTION [J].

KIRBY, AJ ;

VARVOGLIS, AG .

JOURNAL OF THE CHEMICAL SOCIETY B-PHYSICAL ORGANIC, 1968, (02) :135-+

[10] REACTIVITY OF PHOSPHATE ESTERS . MONOESTER HYDROLYSIS [J].

KIRBY, AJ ;

VARVOGLI.AG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1967, 89 (02) :415-&

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