Complexation of nickel(II) and lead(II) cations with the tripodal nitrilo-tris(methylenephenylphosphinic) acid (H3L).: X-ray crystal structure of the dimer [Ni(HL)(DMSO)]2•2DMSO

被引：10

作者：

Cecconi, F

Ghilardi, CA

Gili, P

Midollini, S

Luis, PAL

Lozano-Gorrìn, AD

Orlandini, A

机构：

[1] CNR, Ist Studio Stereochim & Energet Composti Coordina, I-50132 Florence, Italy

[2] Univ La Laguna, Dept Quim Inorgan, Fac Farm, E-38200 Tenerife, Canary Isl, Spain

来源：

INORGANICA CHIMICA ACTA | 2001年 / 319卷 / 1-2期

关键词：

crystal structures; nickel complexes; phosphinates; phosphinate complexes; thermogravimetric analyses;

D O I：

10.1016/S0020-1693(01)00440-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of dimeric complexes have been isolated by the reaction of M(CH3COO)(2). xH(2)O (M-II = Ni, Pb) with nitrilo-tris-(methylenephenylphosphinic) acid (H3L) in dimethylsulfoxide or pyridine or water. A complete single crystal structure determination has been carried out on the nickel derivative, which displays a dimeric structure [Ni(HL)(DMSO)](2). 2DMSO. All the compounds have been characterized through magnetic measurements, thermogravimetric and calorimetric analyses. (C) 2001 Elsevier Science B.V. All rights reserved.

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页码：67 / 74

页数：8

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