Hydrogen-bonded assembly of water and chloride in a 3D supramolecular host

被引：73

作者：

Ghosh, AK

Ghoshal, D

Ribas, J

Mostafa, G

Chaudhuri, NR ^{[1
]}

机构：

[1] Jadavpur Univ, Dept Phys, Jadavpur 700032, Kolkata, India

[2] Indian Assoc Cultivat Sci, Dept Inorgan Chem, Kolkata 700032, India

[3] Univ Barcelona, Dept Quim Inorgan, E-08028 Barcelona, Spain

来源：

CRYSTAL GROWTH & DESIGN | 2006年 / 6卷 / 01期

关键词：

D O I：

10.1021/cg050423i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The hydrogen-bonded water-chloride assembly {[(H2O)(14)Cl-2](2-)}(n), which is stabilized in a template of metal organic supramolecular host (MOSH) {[Cu(phen)(4)(adi)(OH)(2)Cl-2](2+)}(n)(adi = adipate dianion; phen = 1,10-phenanthroline), was isolated. DFT calculations corroborate the X-ray crystal structure of the hydrogen-bonded water-chloride assembly. The variable temperature magnetic study also corroborates the single-crystal structure.

引用

页码：36 / 39

页数：4

共 31 条

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Akabas M. H., 2001, ENCY LIFE SCI

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