Sequential epoxide fragmentation radical cyclizations mediated by samarium(II) iodide

被引：7

作者：

Molander, GA ^{[1
]}

Losada, CD ^{[1
]}

机构：

[1] Univ Colorado, Dept Chem & Biochem, Boulder, CO 80309 USA

来源：

TETRAHEDRON | 1998年 / 54卷 / 22期

基金：

美国国家卫生研究院;

关键词：

D O I：

10.1016/S0040-4020(98)00272-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A sequential reductive coupling process promoted by samarium(II) iodide is described. Cascade epoxide ring opening and two sequential radical cyclizations lead to a variety of bicyclo[m.n.0] systems as mixtures of diastereomers. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：5819 / 5832

页数：14

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