Fluorescent ratiometric sensing of pyrophosphate via induced aggregation of a conjugated polyelectrolyte

被引：88

作者：

Zhao, Xiaoyong ^{[1
]}

Schanze, Kirk S. ^{[1
]}

机构：

[1] Univ Florida, Dept Chem, Gainesville, FL 32611 USA

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 33期

基金：

美国国家科学基金会;

关键词：

MOLECULAR WIRE APPROACH; ALKALINE-PHOSPHATASE; OPTICAL-PROPERTIES; POLYMERS; CHEMOSENSORS; SENSORS; DNA; CONFORMATIONS; PHOTOPHYSICS; ETHYNYLENE);

D O I：

10.1039/c0cc01332c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Direct detection of pyrophosphate (PPi) in aqueous solution is demonstrated using a cationic poly(phenylene-ethynylene) with polyamine side chains. Pyrophosphate-induced polymer aggregation causes a significant spectroscopic change, which in turn allows quantification of dissolved PPi using ratiometric signals.

引用

收藏

页码：6075 / 6077

页数：3

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